Process for preparing aqueous dispersions of copolymers from hydrophilic and hydrophilic monomers, copolymers obtainable therefrom and uses thereof

US6552142B1 · kind B1 · utility

Assignee

• BASF SE

Inventors

• Helmut Meffert · Mannheim, DE
• Maximilian Angel · Mutterstadt, DE

Key dates

• Filing date: Feb 17, 2000
• Grant date: Apr 22, 2003
• Expiry date: Feb 17, 2020

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C08F226/06
• WIPO field: Macromolecular chemistry, polymers
• WIPO sector: Chemistry

Abstract

A description is given of a process for preparing aqueous copolymer dispersions by free-radical polymerization of ethylenically unsaturated monomers in an aqueous solution in which(a) from 10 to 90% by weight of at least one hydrophilic monomer A which has an N-vinyl group and whose polymerisation rate possesses a maximum at pH levels above 7, and(b) from 10 to 90% by weight of at least-one monoethylenically unsaturated hydrophobic monomer B whose polymerisation rate possesses a maximum at pH levels below 7,are copolymerised in the presence of a free-radical initiator system such that in the course of the polymerization the pH falls by from 2 to 5 units.The copolymer dispersions prepared in this way and the copolymers obtainable therefrom are suitable as auxiliaries for pharmaceutical, cosmetic or agrochemical formulations and for preparing paints, coating compositions, sizes, and adhesives.