Method for carrying out radical ethylene high-pressure polymerization while preventing undesired polymer deposits
US6562915B2 · kind B2 · utility
Assignees
Inventors
Key dates
| Filing date | Jul 31, 2002 |
| Grant date | May 13, 2003 |
| Priority date | — |
| Expiry date | Jul 31, 2022 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08F110/02
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
In a process for the polymerization or copolymerization of ethylenically unsaturated monomers in the presence of polymerization initiators which decompose to form free radicals in a continuously operated polymerization apparatus comprising a fresh gas feed line, a precompressor, a postcompressor, a reactor, a pressure maintenance valve, a high-pressure circuit having a high-pressure product separator and a high-pressure circulation gas return line, a product valve and a low-pressure circuit having a low-pressure product separator and a low-pressure circulation gas return line, nitrogen monoxide or oxygen is introduced as inhibitor into the high-pressure circuit, into the low-pressure circuit and/or the precompressor.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.