Polyolefin production

US6583243B2 · kind B2 · utility

Assignee

• Fina Research, S.A. · BE

Inventors

• Abbas Razavi · Mons, BE
• Olivier Miserque · Court-Saint-Etienne, BE

Key dates

• Filing date: Jan 31, 2002
• Grant date: Jun 24, 2003
• Expiry date: Jan 31, 2022

Classification

• Technology area (CPC Y): Emerging Cross-Sectional Technologies
• CPC primary: Y10S526/943
• WIPO field: Macromolecular chemistry, polymers
• WIPO sector: Chemistry

Abstract

A metallocene compound having the general formula: CpAXMQ1Q2Cp′A′X′M′Q1′Q2′ wherein Cp and Cp′ are each independently a substituted or unsubstituted cyclopentadienyl moiety; M and M′ are each independently a metal chosen from Group IV B transition metals and vanadium, and coordinate to Cp and Cp′ respectively; X and X′ are each independently a substituted or unsubstituted Group VA or VIA heteroatom and coordinate to M and M″ respectively; A and A′ are bridging groups between Cp and X and between Cp′ and X′ respectively and are independently chosen from —SiR′2—O—SiR′2—, —SinR′m—, —CnR′m— and —CR′2—SiR′2—CR′2—SiR′2—, in which each R′ is independently H or hydrocarbyl having 1 to 20 carbon atoms, n is an integer in the range 1 to 4 and m=2n; each Q1, Q2 and Q1′ and Q2′ is independently a coordinating group which is hydrogen, halogen or hydrocarbyl having 1 to 20 carbon atoms and each of Q1 and Q1′ is coordinated to both M and M′.