Patent · US Expired

Method for (CO)polymerizing polar and non-polar monomers

US6599996B1 · kind B1 · utility

2Cited by
4References
7Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMay 23, 2002
Grant dateJul 29, 2003
Priority date
Expiry dateMay 23, 2022

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08F12/04
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

In a process for the transition-metal-catalyzed preparation of polymers having a syndiotactic or predominantly syndiotactic structure from vinylaromatic monomers and a process for preparing block copolymers from vinylaromatic monomers and olefinically unsaturated polar monomers, use is made of transition metal compounds of the formula (I) where the substituents and indices have the following meanings:M is scandium, yttrium, lanthanum or a lanthanide metal,R′″ is &mgr;-C3-C20-alkyl,L is a low molecular weight organic compound having Lewis basicity, where n=1 or 0 and at least one n in (I) is 0,m is 1 or 2.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.