Niobium containing zirconium-cerium based solid solutions
US6605264B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Jul 16, 2002 |
| Grant date | Aug 12, 2003 |
| Priority date | — |
| Expiry date | Jul 16, 2022 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02T10/12
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
The present invention relates to high oxygen ion conducting/oxygen storage (OIC/OS) materials, a catalyst employing the OIC/OS materials, and a method for converting hydrocarbons, carbon monoxide and nitrogen oxides using the catalyst. The OIC/OS materials have significantly higher oxygen storage capacity than that predicted based on Ce content due to the unexpected high and facile redox activity of the added niobium. These materials are further characterized by having a tetragonal crystalline structure under oxidizing conditions (in air) up to about 1,200° C. and a cubic crystalline structure in reducing conditions (5% hydrogen) up to about 1,000° C. for 24 hours. These materials comprise, based upon 100 mole % of the metal component in the material, up to about 95 mole % zirconium, up to about 50 mole % cerium, about 0.5 to about 15 mole % rare earth metal(s), alkaline earth metal(s) or a combination thereof, and about 0.5 to about 15 mole % niobium.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.