Activator solid support for metallocene catalysts in the polymerization of olefins, a process for preparing such a support, and the corresponding catalytic system and polymerization process
US6605561B1 · kind B1 · utility
Assignee
Inventors
Key dates
| Filing date | Apr 2, 2001 |
| Grant date | Aug 12, 2003 |
| Priority date | — |
| Expiry date | Apr 2, 2021 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S526/943
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
Activator solid support for metallocenes as catalysts in the polymerization of olefins, characterized in that it consists of a group of support particles for a solid catalytic component, which are formed from at least one porous mineral oxide, the said particles having been modified in order to carry, on the surface, aluminium and/or magnesium Lewis-acid sites of formula: or —Mg—F, the groups coming from a functionalization agent having reacted with —OH radicals carried by the base particles of the support, the functionalization reaction having been followed by a fluorination reaction. The catalytic system according to the invention comprises (a) a metallocene catalyst, which has, if required, been subjected to a prealkylation treatment; (b) a cocatalyst; and (c) an activator solid support for metallocene, as defined above, it being possible for the cocatalyst (b) to be absent if the metallocene catalyst (a) has been prealkylated.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.