Patent · US Expired

Process for polymerization of vinyl chloride

US6617408B2 · kind B2 · utility

3Cited by
14References
7Claims
0Family size

Assignee

Inventor

Key dates

Filing dateMay 25, 2001
Grant dateSep 9, 2003
Priority date
Expiry dateMay 25, 2021

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C407/003
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

The dialkyl peroxydicarbonates with short alkyl chains, preferably diethyl and diisopropyl peroxydicarbonates, are used for the aqueous suspension polymerization of vinyl chloride, in the form of a solution in a dialkyl alkanedicarboxylate which is liquid and insoluble in water. The preferred solvents are hexanedicarboxylates (adipates) derived from adipic acid and from C6-C10 alkanols. The peroxydicarbonate concentration of the said solutions is generally 15-40% by weight. The process according to the invention produces vinyl chloride polymers of improved quality resulting in shaped articles exhibiting markedly fewer fisheyes.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.