Process for preparing a 1,3-alkandiol from 3-hydroxyester
US6617478B2 · kind B2 · utility
Assignees
Inventors
Key dates
| Filing date | Aug 6, 2002 |
| Grant date | Sep 9, 2003 |
| Priority date | — |
| Expiry date | Aug 6, 2022 |
Classification
- Technology area (CPC B)Performing Operations; Transporting
- CPC primaryB01J37/18
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
A process for preparing a 1,3-alkandiol from a 3-hydroxyester, comprises preparing a catalyst by adding an alkaline precipitator to an aqueous copper salt solution to form copper hydroxide particles, and aging the particles following the addition of a colloidal silica thereto; activating the catalyst by reduction with a H2 gas or a H2-containing gas and applying a pressure of about 5 psig to about 2000 psig at a temperature of about 100° C. to about 250° C. in the presence of an activation solvent; and hydrogenating a 3-hydroxyester in a liquid phase slurry with a H2 gas or a H2-containing gas and applying a pressure of about 50 psig to about 3000 psig at a temperature of about 100° C. to about 250° C. in the presence of the activated catalyst and a reaction solvent, whereby a 1,3-alkanediol can be selectively prepared from a 3-hydroxyester with a high yield.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.