Patent · US Expired

Process for regenerating a catalytic redox solution, to include measuring the oxygen dissolved in the regeneration effluent and its application to desulfurization

US6669921B2 · kind B2 · utility

0Cited by
6References
10Claims
0Family size

Assignee

Inventors

Key dates

Filing dateDec 21, 2001
Grant dateDec 30, 2003
Priority date
Expiry dateMar 4, 2022

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/584
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

The present invention relates to a process for regenerating an at least partly reduced catalytic redox solution. The solution includes at least one polyvalent metal chelated by a chelating agent and is circulated in at least one regeneration zone while an oxygen-containing gas is injected into the regeneration zone. The process includes measuring a concentration of oxygen dissolved in a regeneration zone effluent. The process also includes adjusting a flow rate of the at least partly reduce catalytic redox solution entering the at least one regeneration zone and/or an oxygen-containing gas entering the regeneration zone in response to a measured concentration of oxygen, until a concentration of oxygen in the regeneration zone effluent is less than 20% of an amount of oxygen dissolved in water saturated with oxygen. Thus, degradation of the chelating agent in the catalytic redox solution is minimized.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.