Process and products of purification of anhydrosugar alcohols

US6670033B1 · kind B1 · utility

Assignee

• E.I. DU PONT DE NEMOURS AND COMPANY · US

Inventors

• Michael A. Hubbard · Somerville, US
• Michael Wohlers · Eschborn, DE
• Helmut Witteler · Monsheim, DE
• Edward G. Zey · Port Aransas, US
• George Kvakovszky · Port Aransas, US
• Thomas H. Shockley · Port Aransas, US
• Larry F. Charbonneau · Mendham, US
• Norbert Kohle · Flörsheim, DE
• Jochen Rieth · Bad Camberg, DE

Key dates

• Filing date: Nov 27, 2001
• Grant date: Dec 30, 2003
• Expiry date: Nov 27, 2021

Classification

• Technology area (CPC Y): Emerging Cross-Sectional Technologies
• CPC primary: Y10T428/2913
• WIPO field: Macromolecular chemistry, polymers
• WIPO sector: Chemistry

Abstract

A process for the formation of a purified anhydrosugar alcohol is disclosed, whereby the resultant purified anhydrosugar alcohol has a purity of at least 99.8% and is substantially colorless. The anhydrosugar alcohol is purified by distillation, recrystallization from methanol, ethanol or ethylene glycol, melt recrystallization, or a combination thereof. Preferably, the purification is by distillation followed by recrystallization from methanol, ethanol or ethylene glycol. A test for determining the purity of the anhydrosugar alcohol is disclosed, wherein the color of the anhydrosugar alcohol after annealing at a temperature of at least 260° C. for at least four hours is examined. Alternatively, purity can be determined by examination of ultraviolet (UV) transmittance of the purified anhydrosugar alcohol at various wavelengths. The purified anhydrosugar alcohol may be incorporated into a polymer such as a polyester, which may in turn be used to form such articles of manufacturing as containers, optical disks, fibers, sheets and films.