Patent · US Expired

Method of making mercaptoalkylalkoxysilanes

US6680398B1 · kind B1 · utility

10Cited by
7References
42Claims
0Family size

Assignee

Inventors

Key dates

Filing dateAug 16, 2002
Grant dateJan 20, 2004
Priority date
Expiry dateAug 16, 2022

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07F7/1892
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

In a first embodiment of a process for making mercaptoalkylalkoxysilanes, a pH adjusting agent and a sulfide containing compound are mixed in an aqueous phase to provide a pH of 4-9, a phase transfer catalyst is added to the aqueous phase, a haloalkylalkoxysilane is then added to the aqueous phase to form a reaction mixture containing mercaptoalkylalkoxysilanes and water soluble byproducts, and the desired mercaptoalklyalkoxysilanes are separated from the water soluble byproducts. In an alternate embodiment, the haloalkylalkoxysilane, the phase transfer catalyst, and an anhydrous pH adjusting agent such as sulfur dioxide, carbon dioxide, hydrogen sulfide, phosphoric acid, boric acid, and hydrochloric acid, are mixed, then an aqueous solution of a sulfide containing compound is added to form a reaction mixture containing mercaptoalkylalkoxysilanes and water soluble byproducts, and desired mercaptoalklyalkoxysilanes are separated from water soluble byproducts.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.