Patent · US Expired

Process for upgrading fischer-tropsch syncrude using thermal cracking and oligomerization

US6703535B2 · kind B2 · utility

13Cited by
15References
40Claims
0Family size

Assignee

Inventors

Key dates

Filing dateApr 18, 2002
Grant dateMar 9, 2004
Priority date
Expiry dateApr 18, 2022

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S208/95
  • WIPO fieldBasic materials chemistry
  • WIPO sectorChemistry

Abstract

A process for upgrading a Fischer-Tropsch feedstock which comprises (a) recovering from a Fischer-Tropsch reactor a Fischer-Tropsch wax fraction and a Fischer-Tropsch condensate fraction, wherein the Fischer-Tropsch condensate fraction contains alcohols boiling below about 370° C.; (b) contacting the Fischer-Tropsch condensate fraction with a dehydration catalyst in a dehydration zone under dehydration conditions pre-selected to convert at least some of the alcohols present in said fraction into olefins and recovering a first intermediate effluent from said dehydration zone; (c) pyrolyzing the paraffins in the Fischer-Tropsch wax fraction in a thermal cracking zone under thermal cracking conditions pre-selected to crack the Fischer-Tropsch wax molecules to form olefins and collecting a second intermediate effluent from the thermal cracking zone; (d) passing the first and second intermediate effluents recovered from steps (b) and (c) to an oligomerization zone containing an oligomerization catalyst under oligomerization conditions to form an oligomerization mixture having a higher molecular weight than either of said first and second intermediate effluent; (e) hydrofinishing the…

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.