Patent · US Expired

Heat-resistant methacrylic copolymers, production process thereof and optical elements

US6716951B2 · kind B2 · utility

1Cited by
0References
7Claims
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Assignee

Inventors

Key dates

Filing dateJul 22, 2002
Grant dateApr 6, 2004
Priority date
Expiry dateJul 22, 2022

Classification

  • Technology area (CPC G)Physics
  • CPC primaryG02B1/04
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A process for production of methacrylic copolymers, characterized by charging a monomer mixture comprising from 70 to 95% by weight of methyl methacrylate, from 0 to 15% by weight of &agr;-methylstyrene, from 0 to 20% by weight of styrene and from 2 to 15% by weight of maleic anhydride at a molar ratio of the sum of &agr;-methylstyrene and styrene to maleic anhydride laying within the range of 1.0 to 2.5 into a polymerizing vessel containing at least one polymeric membrane layer having an oxygen permeability of 1.5×10−13 (mol·m−2·s−1·Pa−1) or below, sealing the polymerizing vessel, and polymerizing the monomer mixture under heating in a gas phase; a methacrylic copolymer obtained by the production process which is reduced yellowing and shows excellent transparency and heat resistance; and an optical element composed of the methacrylic copolymer.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.