Polymerization process
US6737486B2 · kind B2 · utility
Assignee
Inventor
Key dates
| Filing date | Jul 16, 2002 |
| Grant date | May 18, 2004 |
| Priority date | — |
| Expiry date | Jul 16, 2022 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08F4/00
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
A process for polymerization of vinyl monomers is described comprising polymerizing vinyl monomers in the presence of an initiating system comprising (i) an organic iodide, organic bromide, organic chloride, or an organic sulfur initiator compound, and (ii) a layered material catalyst, and wherein when the initiator compound comprises an organic bromide or organic chloride compound, the initiating system further comprises an iodide or sulfur containing salt compound or a transition metal salt. The present invention provides a novel method for living polymerization of vinyl monomers, which provides a high level of macromolecular control over the polymerization process and which leads to uniform and controllable polymeric products, which may include well-defined structures and complex architectures.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.