Method for polymerising ethylene
US6743871B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | May 5, 2003 |
| Grant date | Jun 1, 2004 |
| Priority date | — |
| Expiry date | May 5, 2023 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08F110/02
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
The invention concerns a method for producing ethylene homopolymers or copolymers comprising at least 90 mol % of units derived from ethylene which consists in: contacting in polymerising conditions, the monomers with a catalytic system including: (a) a catalytic solid comprising a metallocene of a transition metal of groups 4 to 6 of the periodic table containing at least a cyclopentadiene ligand capable of being substituted and a support, (b) at least an organoaluminium compound selected among compounds of general formula (1): AlTx(Y′)yX′z wherein: T is a hydrocarbon group containing 1 to 30 carbon atoms; Y′ is a group selected among —OR′, —SR′ and NR′R″ with R′ and R″ independently representing a hydrocarbon group containing 1 to 30 carbons atoms; X′ is a halogen atom: x verifies the relationship 0<x≦3; y verifies the relationship 0≦y<3; z verifies the relationship 0≦2<3, and x+y+z=3, and (c) at least an ionic antistatic agent.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.