Patent · US Expired

Propylene polymers incorporating polyethylene macromers

US6750307B2 · kind B2 · utility

44Cited by
71References
44Claims
0Family size

Assignee

Inventors

Key dates

Filing dateNov 14, 2002
Grant dateJun 15, 2004
Priority date
Expiry dateNov 25, 2022

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08L2314/06
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A polyolefin product is provided which comprises a branched olefin copolymer having an isotactic polypropylene backbone, polyethylene branches and, optionally, one or more comonomers. The total comonomer content of the branched olefin copolymer is from 0 to 20 mole percent. Also, the mass ratio of the isotactic polypropylene to the polyethylene ranges from 99.9:0.1 to 50:50. Additionally, a process is provided for preparing a branched olefin copolymer which comprises:a) copolymerizing ethylene, optionally with one or more copolymerizable monomers, in a polymerization reaction under conditions sufficient to form copolymer having greater than 40% chain end-group unsaturation;b) copolymerizing the product of a) with propylene and, optionally, one or more copolymerizable monomers, in a polymerization reactor under suitable polypropylene polymerization conditions using a chiral, stereorigid transition metal catalyst capable of producing isotactic polypropylene; andc) recovering a branched olefin copolymer.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.