Patent · US Expired

Gas phase polymerization process

US6753390B2 · kind B2 · utility

47Cited by
12References
45Claims
0Family size

Assignee

Inventors

Key dates

Filing dateFeb 18, 2003
Grant dateJun 22, 2004
Priority date
Expiry dateFeb 18, 2023

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S526/905
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A gas phase polymerization process for producing a polyolefin composition is described, which includes passing a gaseous stream containing hydrogen gas and one or more monomers, including ethylene monomers, through a reactor that includes a fluidized bed, under reactive conditions, in the presence of a catalyst that includes metallocene, to provide a polyolefin composition, wherein in one embodiment the fluidized bulk density is 60% or more of the settled bulk density (or, a voidage of 40% or less); and wherein the voidage is controlled by a number of factors including, in certain embodiments, (a) the reactor temperature being maintained at 100° C. or below; (b) the molar ratio of hydrogen gas to ethylene introduced into the reactor being 0.015 or below.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.