Patent · US Expired

Stabilized fluorine-containing polymer and method for stabilizing fluorine containing polymer

US6777501B1 · kind B1 · utility

3Cited by
11References
4Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 8, 2000
Grant dateAug 17, 2004
Priority date
Expiry dateSep 8, 2020

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08F2810/40
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

To a fluorine-containing polymer, 0.1 to 10% of a compound comprising an alkali metal or an alkaline earth metal in terms of the number of atoms of the alkali metal or the alkaline earth metal based on the total number of the above terminal groups, 0.1 to 10% of ammonia in terms of the number of ammonia molecules based on the total number of the above terminal groups, or 0.1 to 10% of a compound having an ammonium group in terms of the number of the ammonium groups based on the total number of the above terminal groups is added, and heated at a temperature of at least 2000C in an atmosphere containing moisture. By this process, unstable terminal groups such as terminal carboxylic acid groups and coloration caused by such terminal groups are effectively removed from the fluorine-containing polymer, and furthermore unstable bonds in the backbones can be removed. The obtained fluorine-containing polymer contains 1.0×1013 spins/g or less of unpaired electrons on the carbon atoms in terms of a spin density measured with spin resonance at a temperature of 10K.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.