Method for the determination of hexavalent chromium using ultrasonication and strong anion exchange solid phase extraction
US6808931B1 · kind B1 · utility
Assignee
Inventors
Key dates
| Filing date | Oct 10, 2000 |
| Grant date | Oct 26, 2004 |
| Priority date | — |
| Expiry date | Oct 10, 2020 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10T436/255
- WIPO fieldMeasurement
- WIPO sectorInstruments
Abstract
A method for the determination of hexavalent chromium (CrVI) in environmental and industrial hygiene samples is provided. Based on the chemical properties of chromium species in aqueous solutions, a simple, fast, sensitive, and economical field method has been developed and evaluated for the determination of hexavalent chromium (CrVI). Using ultrasonic extraction in combination with a strong anion exchange solid phase extraction (SAE-SPE) technique, the filtration, preconcentration, and isolation of CrVI in the presence of other chromium species and interferents was achieved. The method generally involves: (1) ultrasonication in basic buffer solution to extract CrVI from environmental matrices; (2) strong anionic exchange solid phase extraction to separate CrVI from other chromium species and potential interferents; (3) acidification of the eluate containing the CrVI ions; (4) complexation of CrVI with a complexing agent to form a soluble, colored CrVI-complex; and (5) spectrophotometric determination of the colored CrVI-complex. Preferably, the ultrasonication step is carried out in the presence of a slightly basic ammonium buffer and the complexing agent is 1,5-diphenylcarbazide.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.