Patent · US Expired

Catalyst compounds with &bgr;-diiminate anionic ligands and processes for polymerizing olefins

US6821921B2 · kind B2 · utility

9Cited by
26References
30Claims
0Family size

Assignee

Inventors

Key dates

Filing dateDec 16, 2002
Grant dateNov 23, 2004
Priority date
Expiry dateDec 16, 2022

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08F2410/03
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

The present invention relates to catalyst systems, processes for making such catalysts, intermediates for such catalysts, and olefin polymerization processes using such catalysts wherein such catalyst includes a component represented by the following formula IA: whereinR and R′ independently represent a hydrogen atom, or a substituted or unsubstituted, branched or unbranched hydrocarbyl or organosilyl radical;R1, R2, and R3 independently represent a hydrogen atom, or a substituted or unsubstituted, branched or unbranched hydrocarbyl radical;M is a group IIIB, IVB, VB, VIB, VIIB or VIII transition metal;T independently represents a univalent anionic ligand such as a hydrogen atom, or a substituted or unsubstituted hydrocarbyl, halogeno, aryloxido, arylorganosilyl, alkylorganosilyl, amido, arylamido, phosphido, or arylphosphido group, or two T groups taken together represent an alkylidene or a cyclometallated hydrocarbyl bidentate ligand;L independently represents a sigma donor stabilizing ligand; X, which is optional, represents a relatively weakly coordinated anion; anda=0 to 4 inclusive, b=0 to 4 inclusive, provided a+b≦4.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.