Patent · US Expired

Methods of polymerizing olefin monomers with mixed catalyst systems

US6833416B2 · kind B2 · utility

14Cited by
13References
30Claims
0Family size

Assignee

Inventors

Key dates

Filing dateFeb 27, 2004
Grant dateDec 21, 2004
Priority date
Expiry dateFeb 27, 2024

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08F2410/08
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A method of transitioning catalysts for polyolefin polymerization is provided. In one aspect, the process includes providing a polymerization reactor that includes a first catalyst system, contacting olefin monomers with the first catalyst system to form polyolefin in a first polymerization reaction and introducing a catalyst killer to the polymerization reactor in an amount sufficient to terminate the first polymerization reaction. The method further includes introducing a second catalyst system to the polymerization reactor in the presence of at least a portion of the catalyst killer, wherein the at least a portion of the catalyst killer is an amount sufficient to activate the second catalyst system and contacting olefin monomers with the second catalyst system to form polyolefin in a second polymerization reaction.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.