Process of recovering valuable metals from waste secondary batteries
US6835228B1 · kind B1 · utility
Assignee
Inventors
Key dates
| Filing date | Nov 19, 2003 |
| Grant date | Dec 28, 2004 |
| Priority date | — |
| Expiry date | Nov 19, 2023 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02W30/84
- WIPO fieldMaterials, metallurgy
- WIPO sectorChemistry
Abstract
A process of recovering metals from waste lithium ion/Ni—H/Ni—Cd batteries, wherein the waste batteries are calcined and sieved to generate an ash containing metals and metal oxides. The process includes subjecting the ash to a first dissolution etching treatment, a first filtration treatment to obtain a filtrate containing Cd ions which are crystallized as cadmium sulfate, a second dissolution etching treatment for the filtered solid, and a second filtration treatment to obtain a second filtrate. Fe+3, Al+3 and rare earth metal ions in the second filtrate are precipitated as hydroxides by adding a base to the second filtrate. The remaining solution was extracted and counter-extracted to obtain aqueous solutions of Co and Ni ions, which were subjected separately to a electrolysis to deposit Co and Ni metals. Li ions in the residue solution from the electrolysis of Ni was precipitated as carbonate by adding a soluble carbonate salt.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.