Porous silica granule, method for producing the same, and method for producing synthetic quartz glass powder using the porous silica granule

US6849242B1 · kind B1 · utility

Assignees

• HERAEUS QUARZGLAS GMBH & CO. KG · DE
• SHIN-ETSU QUARTZ PRODUCTS CO., LTD. · JP

Inventors

• Rainer Koeppler · Seligenstadt, DE
• Fritz-Ulrich Kreis · Gelnhausen, DE
• Klaus Arnold · Mandelbachtal, DE
• Hiroshi Matsui · Glen Rock, US
• Kasumi Hoshikawa · Koriyama, JP
• Tsukasa Sakaguchi · Yokohama, JP

Key dates

• Filing date: Sep 28, 2000
• Grant date: Feb 1, 2005
• Expiry date: Sep 5, 2022

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C03C11/00
• WIPO field: Materials, metallurgy
• WIPO sector: Chemistry

Abstract

The granule consists of individual granules approximately spherical in shape, having a pore volume of 0.5 cm3, a mean diameter of pores of 50 nm or less, a specific surface area of 100 m2/g or less, and a bulk density of 0.7 g/cm3 or higher. It is produced by dispersing a fumed silica obtained by hydrolysis of a silicon compound into pure water to obtain a slurry, and drying the slurry. The granule is used for producing high purity synthetic quartz glass powder. The method further comprises: a first heat treatment under an oxygen-containing atmosphere, a second heat treatment in a temperature range of from 600 to 1100° C., and a third heat treatment in a temperature range of from 1100 to 1300° C. under an atmosphere containing hydrogen chloride; and a step of densification comprising calcining the product at a temperature not higher than 1500° C. under vacuum or in an atmosphere of gaseous hydrogen or gaseous helium. To calcine the powder without causing fusion adhesion of the particles, bubbling fluidization of said porous silica granule is conducted by supplying gaseous helium and calcining thereof in a temperature range of from 1000 to 1600° C.