Production of higher olefins

US6875899B2 · kind B2 · utility

Assignee

• ExxonMobil Chemical Patents Inc. · US

Inventors

• Luc Martens · Meise, BE
• John Stephen Godsmark · Grez-Doiceau, BE
• Marcel Janssen · Kessel-Lo, BE
• Georges Marie Karel Mathys · Bierbeek, BE
• Raphael Frans Caers · Edegem, BE
• Hubertus Joseph Beckers · Keerbergen, BE
• J. Richard Shutt · Tervuren, BE
• Eddy Van Driessche · Eeklo, BE

Key dates

• Filing date: Jan 24, 2002
• Grant date: Apr 5, 2005
• Expiry date: Jun 22, 2023

Classification

• Technology area (CPC Y): Emerging Cross-Sectional Technologies
• CPC primary: Y02P30/40
• WIPO field: Organic fine chemistry
• WIPO sector: Chemistry

Abstract

A method of making a higher olefin product from a C4+ fraction separated from the hydrocarbon product produced by an oxygenate to olefin reaction unit. The C4+ fraction primarily contains butenes which may be directed to a higher olefin reaction unit without removing isobutenes, butanes, and/or butadiene. The C4+ fraction is particularly well suited for the production of higher olefins because of its high olefin content, low branching number, and low contaminent levels. The invention is also directed to an olefin product composition that is produced by contacting the C4+ fraction with an oligomerization catalyst. The olefin composition is characterized by a relatively high octene content, and octene with a branching number less than 1.4.