Catalytic generation of hydrogen
US6887455B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Apr 11, 2001 |
| Grant date | May 3, 2005 |
| Priority date | — |
| Expiry date | Dec 28, 2022 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/52
- WIPO fieldMaterials, metallurgy
- WIPO sectorChemistry
Abstract
A process for the catalytic generation of hydrogen by the self-sustaining combination of partial oxidation and steam reforming of a hydrocarbon comprises containing a mixture of the hydrocarbon, an oxygen-containing gas and steam with a catalyst comprising rhodium dispersed on a refractory oxide support material which is a mixture of ceria and zirconia. The hydrocarbons are straight chain or branch chain hydrocarbons having 1 to 15 carbon atoms and include methane, propane, butane, hexane, heptane, normal-octane, iso-octane, naphthas, liquefied petroleum gas and reformulated gasoline petrol and diesel fuels. The hydrogen generation process can be started by feeding the hydrocarbon and air to initiate partial oxidation, before steam is added. The hydrogen generation process can be started by feeding the hydrocarbon and air to initiate partial oxidation, before steam is added. The hydrogen generation process also may be operated in combination with a water-gas shift reaction for the reduction of carbon monoxide in the hydrogen generated.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.