Catalytic composition and process for oligomerizing ethylene, in particular to 1-hexene
US6903042B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Dec 4, 2002 |
| Grant date | Jun 7, 2005 |
| Priority date | — |
| Expiry date | Dec 17, 2022 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/52
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
A catalytic composition for oligomerizing ethylene, in particular to 1-hexene, is obtained by mixing at least one chromium carboxylate characterized in that it also contains a free carboxylic acid in a set proportion, with at least one aryloxy compound of an element M selected from the group formed by magnesium, calcium, strontium and barium, with general formula M(RO)2-nXn in which RO is an aryloxy radical containing 6 to 80 carbon atoms, X is a halogen atom or a hydrocarbyl radical containing 1 to 30 carbon atoms and n is a whole number that can take the values 0 or 1, and with at least one hydrocarbylaluminum compound selected from the group formed by tris(hydrocarbyl)-aluminum compounds, chlorinated or brominated hydrocarbylaluminum compounds and aluminoxanes.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.