Patent · US Expired

Polyoxometallate catalysts and catalytic processes

US6914029B2 · kind B2 · utility

9Cited by
16References
19Claims
0Family size

Assignee

Inventors

Key dates

Filing dateNov 1, 2002
Grant dateJul 5, 2005
Priority date
Expiry dateJan 18, 2023

Classification

  • Technology area (CPC B)Performing Operations; Transporting
  • CPC primaryB01J37/082
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

An active and selective hydrocarbon partial oxidation catalyst comprises an activated partially-reduced polyoxometallate, preferably niobium polyoxomolybdate, that is prepared from a suitable polyoxoanion, which has been exchanged with a suitable cation and activated by heating to an activation effective temperature in the presence of a suitable reducing agent such as pyridinium. C3 and C4 hydrocarbons may be partially oxidized selectively to acrylic acid and maleic acid.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.