Gradient cathode material for lithium rechargeable batteries
US6921609B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Feb 11, 2002 |
| Grant date | Jul 26, 2005 |
| Priority date | — |
| Expiry date | Aug 11, 2022 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02E60/10
- WIPO fieldElectrical machinery, apparatus, energy
- WIPO sectorElectrical engineering
Abstract
A composition suitable for use as a cathode material of a lithium battery includes a core material having an empirical formula LixM′zNi1−yM″yO2. “x” is equal to or greater than about 0.1 and equal to or less than about 1.3. “y” is greater than about 0.0 and equal to or less than about 0.5. “z” is greater than about 0.0 and equal to or less than about 0.2. M′ is at least one member of the group consisting of sodium, potassium, nickel, calcium, magnesium and strontium. M″ is at least one member of the group consisting of cobalt, iron, manganese, chromium, vanadium, titanium, magnesium, silicon, boron, aluminum and gallium. A coating on the core has a greater ratio of cobalt to nickel than the core. The coating and, optionally, the core can be a material having an empirical formula Lix1Ax2Ni1−y1−z1Coy1Bz1Oa. “x1” is greater than about 0.1 a equal to or less than about 1.3. “x2,” “y1” and “z1” each is greater than about 0.0 and equal to or less than about 0.2. “a” is greater than 1.5 and less than about 2.1. “A” is at least one element selected from the group consisting of barium, magnesium, calcium and strontium. “B” is at least one element selected from the group consisting of boron,…
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.