Zirconium phosphate, hafnium phosphate and method of making same
US6936175B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Jul 15, 2002 |
| Grant date | Aug 30, 2005 |
| Priority date | — |
| Expiry date | May 14, 2023 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S210/903
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
The invention relates to zirconium phosphate of H form which is characterized by a 31P NMR spectra comprising peaks at −4.7 ppm, −12.8 ppm and −17.0 ppm (all peaks being in a range of ±0.5 ppm). Also featured is a Na form of the material. The zirconium phosphate material is characterized by a unique surface area, pore size distribution and surface morphology, as well as by an affinity for NH4+ ions and moisture insensitivity. Also featured is hafnium phosphate characterized by moisture insensitivity. The zirconium phosphate may be amorphous and possess a framework-type structure. The inventive method of making zirconium phosphate includes the steps of heating an aqueous mixture including a zirconium compound and a phosphorous-containing reagent at a temperature of at least 120° C. to form a reaction product, and treating the reaction product with acid at a temperature of at least 60° C.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.