Patent · US Expired

Bimetallic catalyst for producing polyethylene resins with bimodal molecular weight distribution, its preparation and use

US6964937B2 · kind B2 · utility

12Cited by
7References
25Claims
0Family size

Assignee

Inventors

Key dates

Filing dateApr 10, 2001
Grant dateNov 15, 2005
Priority date
Expiry dateApr 10, 2021

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S526/943
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

Bimetallic catalyst for producing polyethylene resins with a bimodal molecular weight distribution, its preparation and use. The catalyst is obtainable by a process which includes contacting a support material with an organomagnesium component and carbonyl-containing component. The support material so treated is contacted with a non-metallocene transition metal component to obtain a catalyst intermediate, the latter being contacted with an aluminoxane component and a metallocene component. This catalyst may be further activated with, e.g., alkylaluminum cocatalyst, and contacted, under polymerization conditions, with ethylene and optionally one or more comonomers, to produce ethylene homo- or copolymers with a bimodal molecular weight distribution and improved resin swell properties in a single reactor. These ethylene polymers are particularly suitable for blow molding applications.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.