Method for removal of MW176 cyclic acetal formed during the production of 1,3-propanediol
US6969779B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Oct 1, 2003 |
| Grant date | Nov 29, 2005 |
| Priority date | — |
| Expiry date | May 3, 2024 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07C29/88
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
The present invention is an improvement upon the process for the production of 1,3-propanediol (PDO) wherein an aqueous solution of 3-hydroxypropanal (HPA) is formed, and the HPA is subjected to hydrogenation to produce a crude PDO mixture comprising PDO, water, MW176 acetal, and high and low volatility materials, wherein the crude PDO mixture is dried to produce a first overhead stream comprising water and some high volatility materials and a dried crude PDO mixture as a first distillate bottoms stream comprising PDO, MW176 acetal, and low volatility materials, and wherein the dried crude PDO mixture is distilled to produce a second overhead stream comprising some high volatility materials, a middle stream comprising PDO and MW176 acetal, and a second distillate bottoms stream comprising PDO and low volatility materials. The improvement on this process comprises treating the crude PDO mixture and/or the dried crude PDO mixture and/or the PDO product with an acidic zeolite, an acid form cation exchange resin, or a soluble acid to convert the MW176 cyclic acetal to more volatile materials which can be easily separated from PDO by distillation.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.