Patent · US Expired

Catalysts for the oxidation of unsaturated aldehydes to produce carboxylic acids and methods of making the same

US6989347B2 · kind B2 · utility

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28References
13Claims
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Assignee

Inventors

Key dates

Filing dateApr 25, 2002
Grant dateJan 24, 2006
Priority date
Expiry dateOct 28, 2022

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/582
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A catalyst composition for the production of carboxylic acids by the oxidation of the corresponding unsaturated aldehydes, and methods for making and using the catalyst compositions. The catalysts include compositions of the formula:MoaVbAlcXdYeOzwherein X is at least one element selected from W and Mn; Y is at least one element selected from Pd, Sb, Ca, P, Ga, Ge, Si, Mg, Nb, and K; a is 1; b is 0.01–0.9; c is 0<0.2; d is 0<0.5; e is 0<0.5; and z is an integer representing the number of oxygen atoms required to satisfy the valency of the remaining elements in the composition. Using the catalyst composition of the present invention, one may effectively oxidize the desired starting materials at relatively high levels of conversion, selectivity, and productivity, and with minimal side products.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.