Patent · US Expired

Process for preparation of graft polymers

US7049373B2 · kind B2 · utility

82Cited by
33References
34Claims
0Family size

Assignee

Inventors

Key dates

Filing dateDec 21, 2001
Grant dateMay 23, 2006
Priority date
Expiry dateApr 22, 2023

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08F299/00
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A polymerization process is provided for the preparation of graft (co)polymers. An embodiment of the polymerization process of the present invention comprises copolymerizing macromonomers with (co)monomers utilizing a macroinitiator to form a graft (co)polymer. A further embodiment of a polymerization process of the present invention comprises (co)polymerizing macromonomers and monomers with a graft copolymer macroinitiator to form a block-graft (co)polymer. Another embodiment of the process of the present invention comprises (co)polymerizing macromonomers and monomers with a compatible macroinitiator. The chemical and structural properties of the product graft (co)polymer may be controlled by use of a compatible macroinitiator and the functional group on the macromonomer which effect the relative rates of incorporation of the macromonomer and the monomer. Graft (co)polymers may be prepared with homogeneous or heterogeneous distribution of grafts. In a further embodiment of the present invention, a copolymer with well-defined branches or grafts with predetermined molecular weights and low polydispersities can be obtained by preparing macromonomers by a living or a living/controlled…

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.