Patent · US Expired

Process for the preparation of ωbenzyl esters of amino diacids and of alkanesulphonates of these esters, and these alkanesulphonates

US7078564B2 · kind B2 · utility

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21Claims
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Assignee

Inventors

Key dates

Filing dateDec 17, 2003
Grant dateJul 18, 2006
Priority date
Expiry dateJan 28, 2024

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C229/24
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

The invention relates to a process for the preparation of an ω-benzyl ester of an amino diacid, characterized in that the amino diacid is reacted with a benzyl alcohol derivative of formula (I) in which the R1 substituent or substituents, which are identical or different, represent a hydrogen atom, a C1 to C4 alkyl group, a C1 to C4 alkoxy group or a halogen atom and n is equal to 1, 2 or 3, in the presence of at least one mol per mole of the amino diacid of an alkanesulphonic acid, optionally in the presence of a solvent.The intermediate alkanesulphonates of the ω-benzyl esters of amino diacids and the ω-benzyl esters of amino diacids are obtained with a good yield and an excellent purity by virtue of this process.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.