Hot solids gasifier with CO2 removal and hydrogen production
US7083658B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | May 29, 2003 |
| Grant date | Aug 1, 2006 |
| Priority date | — |
| Expiry date | Sep 30, 2024 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P30/00
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
A gasifier 10 includes a first chemical process loop 12 having an exothermic oxidizer reactor 14 and an endothermic reducer reactor 16. CaS is oxidized in air in the oxidizer reactor 14 to form hot CaSO4 which is discharged to the reducer reactor 16. Hot CaSO4 and carbonaceous fuel received in the reducer reactor 16 undergo an endothermic reaction utilizing the heat content of the CaSO4, the carbonaceous fuel stripping the oxygen from the CaSO4 to form CaS and a CO rich syngas. The CaS is discharged to the oxidizer reactor 14 and the syngas is discharged to a second chemical process loop 52. The second chemical process loop 52 has a water-gas shift reactor 54 and a calciner 42. The CO of the syngas reacts with gaseous H2O in the shift reactor 54 to produce H2 and CO2. The CO2 is captured by CaO to form hot CaCO3 in an exothermic reaction. The hot CaCO3 is discharged to the calciner 42, the heat content of the CaCO3 being used to strip the CO2 from the CaO in an endothermic reaction in the calciner, with the CaO being discharged from the calciner 42 to the shift reactor 54.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.