Method of reducing NOx in diesel engine exhaust
US7090811B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Dec 11, 2003 |
| Grant date | Aug 15, 2006 |
| Priority date | — |
| Expiry date | Feb 9, 2025 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02T10/12
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
This invention provides a method of reducing nitrogen oxides in an oxygen containing exhaust stream using ethanol as a reductant for plasma-assisted selective catalytic reduction. The exhaust gas, generated from a diesel engine or other lean-burn power source, comprises nitrogen oxides, especially NO. Ozone generated from a plasma reactor is injected into the exhaust stream to convert NO to NO2 and the plasma injection is followed by the addition of ethanol. The NO2 is then reduced by contacting the exhaust stream with a dual-bed catalytic reactor comprising BaY (or NaY) and CuY zeolite catalysts in the presence of ethanol as the reductant. The plasma power density and the molar ratio of ethanol to NOx fed to the catalytic reactor are controlled as a function of the catalyst temperature for the best performance of the plasma-catalyst system. An average conversion of NOx to N2 of at least 90% is achieved over the temperature range of 200–400° C.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.