Patent · US Expired

Internally circulating fluidized bed membrane reactor system

US7141231B2 · kind B2 · utility

1Cited by
6References
13Claims
0Family size

Assignee

Inventors

Key dates

Filing dateAug 11, 2003
Grant dateNov 28, 2006
Priority date
Expiry dateAug 23, 2024

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC01B2203/82
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

This invention relates to a novel fluidized bed membrane reactor for autothermal operations. More particularly, this invention pertains to a unique fluidized bed membrane reactor which includes internal catalyst solids circulation for conveying heat between a reforming zone and an oxidation zone. A method of producing hydrogen gas from a hydrocarbon gas and steam comprising forming a fluidized bed of a suitable particulate catalyst in a reactor, wherein the catalyst is disposed in the reactor in two reaction modes, the first being an endothermic dehydrogenation reaction mode and the second being an exothermic oxidation or partial oxidation reaction mode, introducing a mixture of steam and hydrocarbon gas into the bottom of the fluidized bed to fluidize the particulate catalyst and form the fluidized bed, reacting the steam and hydrocarbon gas within the first endothermic dehydrogenation reaction mode to produce hydrogen gas, separating said hydrogen gas from other gases in the first endothermic dehydrogenation reaction mode as molecular or atomic hydrogen through a perm-selective membrane that permits the transfer of hydrogen therethrough while preventing or minimizing the transmis…

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.