Composite material and method for preparation thereof
US7175916B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Jan 9, 2002 |
| Grant date | Feb 13, 2007 |
| Priority date | — |
| Expiry date | Jan 9, 2022 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10T428/31938
- WIPO fieldSurface technology, coating
- WIPO sectorChemistry
Abstract
A composite of a resin member bonded to a vulcanized rubber member is obtained with using a rubber member vulcanized with a radical-generating agent (e.g., an organic peroxide) and a thermoplastic resin having at least 2 atoms, on average, selected from H and S atom per molecule, each atom having not less than 0.006 of an orbital interaction energy coefficient S represented by the following formula (1):S=(CHOMO,n)2/|Ec−EHOMO,n|+(CLUMO,n)2/|Ec−ELUMO,n| (1)wherein Ec: an orbital energy (eV) of a radical, CHOMO,n: a molecular-orbital coefficient of a highest occupied molecular orbital (HOMO) of an n-th H or S atom constituting a basic unit of the resin, EHOMO,n: an orbital energy (eV) of the HOMO, CLUMO,n: a molecular-orbital coefficient of a lowest unoccupied molecular orbital (LUMO) of the n-th H or S atom constituting the basic unit of the resin, ELUMO,n: an orbital energy (eV) of the LUMO, and above all represent a value calculated by a semiempirical molecular orbital method MOPACPM3. The thermoplastic resin includes a polyamide, a polyester, a PPE, a POM, a PPS, a polyolefinic resins, and the unvulcanized rubber may comprise a vulcanization-activating having plural polymerizabl…
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.