Hydrogenation catalyst composition and process for hydrogenation of conjugated diene polymer
US7186782B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Mar 23, 2005 |
| Grant date | Mar 6, 2007 |
| Priority date | — |
| Expiry date | Apr 28, 2025 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S525/94
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
A process for hydrogenation of an unsaturated polymer. The conjugated diene polymer in an inert organic solvent is brought into contact with hydrogen in the presence of a hydrogenation catalyst composition to selectively hydrogenate the unsaturated double bonds in the conjugated diene units of the conjugated diene polymer. The hydrogenation catalyst composition includes: (a) a titanium compound; (b) a compound represented by formula (II) or formula (III):wherein L1 is a Group IVA element, L2 is a Group IVA element, R3 is C1–C12 alkyl or C1–C12 cycloalkyl, R4 is C2–C12 alkyl or C3–C12 cycloalkyl, and X1, X2, and X3 can be the same or different and are C1–C12 alkyl, C1–C12 alkoxy, C1–C12 cycloalkoxy, phenyl, or phenoxy; and (c) a trialkylaluminum compound.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.