Patent · US Expired

Plasticizer-free-ion-detective sensors

US7208121B2 · kind B2 · utility

4Cited by
14References
24Claims
0Family size

Assignee

Inventors

Key dates

Filing dateDec 5, 2002
Grant dateApr 24, 2007
Priority date
Expiry dateJan 7, 2024

Classification

  • Technology area (CPC G)Physics
  • CPC primaryG01N27/3335
  • WIPO fieldMeasurement
  • WIPO sectorInstruments

Abstract

A plasticizer-free ion detective sensor for detecting a target ion in a sample is provided. The sensor comprises a copolymer of methacrylate monomers with pendant alkyl groups of different length, and an ionophore for detecting the target ion. The copolymer matrix of the present invention may be in a form of membrane or particles. The sensors of the present invention may be Carrier-based ion-selective electrodes (ISEs) or optodes such as thin film ion-specific optodes or particle-based optodes. The ionophore may be a target ionophore selective for a target ion H+, Li+, Na+, K+, Ca2+, or Mg2+. The ion detective sensor of the present invention may further include an ion exchanger such as halogenated carboranes. Also provided is an ion detective sensor comprising halogenated carboranes as ion exchangers. Particularly, trimethylammonium-2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12 undecabromocarborane (TMAUBC) is used as ion exchangers.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.