Method for preparing sulfonated polystyrene for polymer electrolyte of fuel cell
US7244791B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Oct 27, 2004 |
| Grant date | Jul 17, 2007 |
| Priority date | — |
| Expiry date | Mar 11, 2025 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P70/50
- WIPO fieldElectrical machinery, apparatus, energy
- WIPO sectorElectrical engineering
Abstract
A method for preparing sulfonated polystyrene, whereby a styrene monomer having a sulfonyl chloride is prepared by reacting p-styrene sulfonic acid salt with a chloride, a styrene-based polymer having the sulfonyl chloride is synthesized by the polymerization of a p-styrene sulfonyl chloride monomer and optionally at least one monomer of a styrene and an acrylic monomer, the styrene-based polymer having the sulfonyl chloride is treated with an inorganic base aqueous solution to change the sulfonyl chloride into a SO3M group where M is an alkali metal, and treated with an acidic aqueous solution to prepare a styrene-based polymer having a sulfonic acid group. The styrene-based polymer having the sulfonic acid group prepared according to the process of the present invention has high proton conductivity and good mechanical properties.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.