Diaminopyrazole derivatives and their use for oxidation dyeing of keratinous fibres

US7250063B2 · kind B2 · utility

Assignee

• L'Oreal · FR

Inventors

• Thilo Fessmann · Aulnay-sous-Bois, FR
• Eric Terranova · Grasse, FR

Key dates

• Filing date: Nov 29, 2001
• Grant date: Jul 31, 2007
• Expiry date: Nov 29, 2021

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C07D405/06
• WIPO field: Organic fine chemistry
• WIPO sector: Chemistry

Abstract

The invention concerns novel diaminopyrazole derivatives of formula (I), wherein: R1 represents C1-C6 alkyl or C2-C6, preferably up to C4, alkenyl, linear or branched, bearing at least a substituent selected among OR, NHR, NRR′, SR, SO2R, COOH, CONH2, CONRR′, PO(OH)2, SH, SO3X, a non-cationic heterocycle, Cl, Br or I−; X represents H, Na, K or NH4; R and R′, identical or different, represent C1-C6 alkyl or C2-C6, preferably up to C4, alkenyl, linear or branched, unsubstituted or substituted by one or several functional groups selected among OH, NH2, OR, NHR, NRR′, SR, SOR, SO2R, COOH, CONH2, CONRR′, PO(OH)2, SH, SO3X, a non-cationic heterocycle, Cl, Br or I, X, R and R′ having the definitions mentioned above; R2 represents H, or C1-C6 alkyl or C2-C6, preferably up to C4, alkenyl, linear or branched, unsubstituted or substituted by one or several functional groups selected among OH, NH2, OR, NHR, NRR′, SR, SOR, SO2R, COOH, CONH2, CONRR′, PO(OH)2, SH, SO3X, a non-cationic heterocycle, Cl, Br or I, X, R and R′ having the definitions mentioned above; and their physiologically acceptable salts, and their use for oxidation dyeing of keratinous fibres, in particular human hair.