Methods for polymerizing macrocyclic polyester oligomers using catalyst promoters
US7256241B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Jan 10, 2006 |
| Grant date | Aug 14, 2007 |
| Priority date | — |
| Expiry date | Jan 10, 2026 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10T428/31786
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
The invention provides methods and formulations involving the use of promoters that accelerate the polymerization of macrocyclic polyester oligomers (MPOs). For example, in certain embodiments, the invention provides blends of macrocyclic polyester oligomer (MPO), catalyst, and promoter that are substantially stable at ambient temperature for a period of time. The blend material may be stored without premature polymerization of MPO or deactivation of catalyst. The invention also provides processes employing one-part, ready-to-polymerize blends that contain MPO, catalyst, and promoter, as well as processes in which the catalyst and promoter are used in separate streams and are contacted when it is desired to accelerate polymerization of MPO. Methods of the invention offer advantages in the manufacture of thermoplastic parts and composites, due at least in part to the unique properties of MPO.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.