Patent · US Expired

Microporous PVDF films

US7338692B2 · kind B2 · utility

61Cited by
11References
9Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 12, 2003
Grant dateMar 4, 2008
Priority date
Expiry dateJan 29, 2025

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10T428/3154
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

Shaped microporous articles are produced from polyvinylidene fluoride (PVDF) and nucleating agents using thermally induced phase separation (TIPS) processes. The shaped microporous article is oriented in at least one direction at a stretch ratio of at least approximately 1.1 to 1.0. The shaped article may also comprise a diluent, glyceryl triacetate. The shaped microporous article may also have the micropores filled with a sufficient quantity of ion conducting electrolyte to allow the membrane to function as an ion conductive membrane. The method of making a microporous article comprises the steps of melt blending polyvinylidene fluoride, nucleating agent and glyceryl triacetate; forming a shaped article of the mixture; cooling the shaped article to cause crystallization of the polyvinylidene fluoride and phase separation of the polyvinylidene fluoride and glyceryl triacetate; and stretching the shaped article in at least one direction at a stretch ratio of at least approximately 1.1 to 1.0.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.