Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7361791B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | May 24, 2007 |
| Grant date | Apr 22, 2008 |
| Priority date | — |
| Expiry date | May 24, 2027 |
Classification
- Technology area (CPC B)Performing Operations; Transporting
- CPC primaryB01J2523/00
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
A catalyst for production of unsaturated aldehydes, such as methacrolein, by gas phase catalytic oxidation of olefins, such as isobutylene, contains oxides of molybdenum, bismuth, iron, cesium and, optionally, other metals. The catalyst has a certain relative amount ratio of cesium to bismuth, a certain relative amount ratio of iron to bismuth and a certain relative amount ratio of bismuth, iron, cesium and certain other metals to molybdenum and, optionally, tungsten. For a catalyst of the formula:Mo12BiaWbFecCodNieSbfCsgMghZniPjOxwherein a is 0.1 to 1.5, b is 0 to 4, c is 0.2 to 5.0, d is 0 to 9, e is 0 to 9, f is 0 to 2.0, g is from 0.4 to 1.5, h is 0 to 1.5, i is 0 to 2.0, j is 0 to 0.5 and x is determined by the valences of the other components, c:g=3.3-5.0, c:a=2.0-6.0 and (3a+3c+2d+2e+g+2h+2i)/(2×12+2b)=0.95-1.10.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.