Halogenated oxime derivatives and the use thereof

US7399577B2 · kind B2 · utility

Assignee

• Ciba Specialty Chemicals Corporation · US

Inventors

• Hitoshi Yamato · Takarazuka, JP
• Toshikage Asakura · Darreh Shahr, IR
• Akira Matsumoto · Yokohama, JP
• Peter Murer · Oberwil, CH
• Tobias Hintermann · Therwil, CH

Key dates

• Filing date: Feb 9, 2004
• Grant date: Jul 15, 2008
• Expiry date: Jul 3, 2024

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C07C2603/40
• WIPO field: Organic fine chemistry
• WIPO sector: Chemistry

Abstract

Compounds of the formula (I) or (II) wherein R1 is C1-C10haloalkylsulfonyl, halobenzenesulfonyl, C2- C10haloalkanoyl, halobenzoyl; R2 is halogen or C1-C10 haloalkyl; Arl is phenyl, biphenylyl, fluorenyl, naphthyl, anthracyl, phenanthryl, or heteroaryl, all of which are optionally substituted; Ar′1 is for example phenylene, naphthylene, diphonylene, heteroarylene, oxydiphenylene, phenyleneD-D1-D-phenylene or —Ar′1-A1—Y1-A1—Ar′1—; wherein these radicals optionally are substituted; Ae′, is phenylene, naphthylene, anthracylene, phenanthrylene, or heteroarylene, all optionally substituted; A, is for example a direct bond, —0—, —S—, or —NR6—; Y, inter alia is C1-C18alkylene; X is halogen; D is for example —0—, —S— or —NR6—; D, inter alia is C1-C18alkylene; are particularly suitable as photolatent acids in ArF resist technology.