Continuous process for the hydrogenation of nitriles or nitro compounds to amines
US7453012B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Jan 20, 2003 |
| Grant date | Nov 18, 2008 |
| Priority date | — |
| Expiry date | Jul 23, 2024 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/584
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
A process for the hydrogenation of compounds comprising nitrile or nitro functional groups to amine, aminonitrile or aminonitro compounds is provided. The process can be a continuous process conducted in the presence of a heterogeneous hydrogenation catalyst in divided form and a basic compound. The reaction can be conducted in a stirred reactor comprising an external loop for circulating the reaction mixture, allowing one portion of the hydrogenated products to be separated without withdrawing the catalyst, by using tangential filtration. The process may be especially useful in the hydrogenation of adiponitrile to an aminocapronitrile/hexamethylenediamine mixture.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.