Glass-ceramic seals for use in solid oxide fuel cells
US7470640B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Oct 11, 2006 |
| Grant date | Dec 30, 2008 |
| Priority date | — |
| Expiry date | Nov 22, 2026 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02E60/50
- WIPO fieldMaterials, metallurgy
- WIPO sectorChemistry
Abstract
The invention is directed to highly crystalline, frit-sintered glass-ceramic materials and seals made using them that are suitable for solid oxide fuel cell applications. The seals have a coefficient of thermal expansion in the range of 70-130×10−7° C., preferably 85-115×10−7° C. The glass-ceramic materials have a crystalline component and a glass component, the crystalline component being>50% of the glass-ceramic and the glass component being<50%. In one preferred embodiment the crystalline component is >75%. Regarding the crystalline component only,>50% of the crystals in the crystalline component of the glass-ceramic has a structure selected from the structural groups represented by walstromite, cyclowollastonite, μ-(Ca,Sr)SiO3, kalsilite, kaliophilite and wollastonite (the primary crystalline phase) and the remaining <50% of the crystalline component is at least one secondary crystalline phase. Generally, the glass-ceramics of the invention are useful as metal-to-metal, metal-to-ceramic and ceramic-to-ceramic sealing agents.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.