Patent · US Expired

Catalyst for propylene polymerization

US7504352B2 · kind B2 · utility

0Cited by
28References
10Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMay 3, 2002
Grant dateMar 17, 2009
Priority date
Expiry dateJul 5, 2024

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08F110/06
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A catalyst for use in the formation of polypropylene is disclosed that comprises a titanium compound having at least one titanium-halogen bond, supported on an activated, amorphous magnesium dihalide support that is essentially free of alkoxy functionality, with a titanium metal content of no more than about 2 wt %, based on the weight of the support, and an internal donor component. This catalyst is made by a: forming a combination of titanium tetrachloride, magnesium-containing compound that can be converted to magnesium dihalide and internal electron donor in an aromatic hydrocarbon solvent and bringing that combination to elevated temperature to form an intermediate product; washing the intermediate product with an aromatic hydrocarbon solvent at elevated temperature to produce a washed product and a supernatant followed by decantation of the supernatant therefrom; treating the washed product with titanium tetrachloride in an aromatic hydrocarbon solvent to form a treated product and a supernatant followed by heating of the treated product and supernatant, decantation of the supernatant therefrom, and washing of the treated product with an aromatic hydrocarbon solvent at elevat…

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.