Liquid-liquid interfacial synthetic method for nanosemiconductor luminous material
US7582543B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Mar 7, 2005 |
| Grant date | Sep 1, 2009 |
| Priority date | — |
| Expiry date | Jul 2, 2026 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC01P2004/64
- WIPO fieldBasic materials chemistry
- WIPO sectorChemistry
Abstract
The present invention provides a process for producing a nanosemiconductor luminous material on a liquid-liquid interface, comprising the steps of: a) an oxide of a Group IIB metal and a carboxylic acid with 2-18 carbon atoms or an oleic acid reacting with each other in a solvent at 150-300° C. for 5-30 min, wherein the mol ratio of the oxide to the acid being 1˜5:5˜1; b) adding trioctylphosphine oxide and trioctylphosphine with a mol ratio of trioctylphosphine oxide to trioctylphosphine of 10˜1:1˜10 and a mol ratio of the total mol numbers of trioctylphosphine oxide to the oxide of 10˜1:1˜10; c) adding an aqueous solution of at least one alkaline/alkaline earth metal chalcogenide in a mol ratio of the chalcogenide to the oxide of 10˜1:1˜10; and d) reacting at 20-100° C. for 0.5˜10 h to obtain a sol containing a semiconductor nanoparticle. The produced semiconductor nanoparticle can emit a wavelength-adjustable visible light under a UV lamp.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.